MersV1, Main, Exploration, bibRecord, 002290

2-Amino-5-methylpyridinium dibromoiodate

Identifieur interne : 002290 ( Main/Exploration ); précédent : 002289; suivant : 002291

2-Amino-5-methylpyridinium dibromoiodate

Auteurs : Salim F. Haddad [Jordanie] ; Basem F. Ali [Jordanie] ; Rawhi Al-Far [Jordanie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.

RBID : PMC:3435817

Abstract

In the title salt, C₆H₉N₂⁺·Br₂I⁻, the cation is essentially planar (r.m.s. deviation = 0.0062 Å for the non-H atoms) while the anion is almost linear with a Br—I—Br angle of 177.67 (2)°. The crystal packing shows two anions and two cations connected via N—H⋯Br and (pyridine)N—H⋯Br hydrogen-bonding interactions, forming centrosymmetric tetramers with R₄⁴(16) ring motifs. Very weak offset aromatic π–π stacking interactions [centroid-centroid separation = 4.038 (4), slippage = 1.773 Å] also occur.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435817

DOI: 10.1107/S1600536812036136
PubMed: 22969663
PubMed Central: 3435817

Affiliations:

Jordanie

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">2-Amino-5-methylpyridinium dibromoiodate</title>
<author><name sortKey="Haddad, Salim F" sort="Haddad, Salim F" uniqKey="Haddad S" first="Salim F." last="Haddad">Salim F. Haddad</name>
<affiliation wicri:level="1"><nlm:aff id="a">Department of Chemistry, The University of Jordan, Amman 11942,<country>Jordan</country>
</nlm:aff>
<country xml:lang="fr">Jordanie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Ali, Basem F" sort="Ali, Basem F" uniqKey="Ali B" first="Basem F." last="Ali">Basem F. Ali</name>
<affiliation wicri:level="1"><nlm:aff id="b">Department of Chemistry, Al al-Bayt University, Mafraq 25113,<country>Jordan</country>
</nlm:aff>
<country xml:lang="fr">Jordanie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Al Far, Rawhi" sort="Al Far, Rawhi" uniqKey="Al Far R" first="Rawhi" last="Al-Far">Rawhi Al-Far</name>
<affiliation wicri:level="1"><nlm:aff id="c">Faculty of Science and IT, Al-Balqa’a Applied University, Salt,<country>Jordan</country>
</nlm:aff>
<country xml:lang="fr">Jordanie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PMC</idno>
<idno type="pmid">22969663</idno>
<idno type="pmc">3435817</idno>
<idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435817</idno>
<idno type="RBID">PMC:3435817</idno>
<idno type="doi">10.1107/S1600536812036136</idno>
<date when="2012">2012</date>
<idno type="wicri:Area/Pmc/Corpus">000990</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000990</idno>
<idno type="wicri:Area/Pmc/Curation">000990</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000990</idno>
<idno type="wicri:Area/Pmc/Checkpoint">001318</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">001318</idno>
<idno type="wicri:source">PubMed</idno>
<idno type="RBID">pubmed:22969663</idno>
<idno type="wicri:Area/PubMed/Corpus">001D50</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">001D50</idno>
<idno type="wicri:Area/PubMed/Curation">001D50</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">001D50</idno>
<idno type="wicri:Area/PubMed/Checkpoint">001D19</idno>
<idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">001D19</idno>
<idno type="wicri:Area/Ncbi/Merge">000993</idno>
<idno type="wicri:Area/Ncbi/Curation">000993</idno>
<idno type="wicri:Area/Ncbi/Checkpoint">000993</idno>
<idno type="wicri:Area/Main/Merge">002315</idno>
<idno type="wicri:Area/Main/Curation">002290</idno>
<idno type="wicri:Area/Main/Exploration">002290</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">2-Amino-5-methylpyridinium dibromoiodate</title>
<author><name sortKey="Haddad, Salim F" sort="Haddad, Salim F" uniqKey="Haddad S" first="Salim F." last="Haddad">Salim F. Haddad</name>
<affiliation wicri:level="1"><nlm:aff id="a">Department of Chemistry, The University of Jordan, Amman 11942,<country>Jordan</country>
</nlm:aff>
<country xml:lang="fr">Jordanie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Ali, Basem F" sort="Ali, Basem F" uniqKey="Ali B" first="Basem F." last="Ali">Basem F. Ali</name>
<affiliation wicri:level="1"><nlm:aff id="b">Department of Chemistry, Al al-Bayt University, Mafraq 25113,<country>Jordan</country>
</nlm:aff>
<country xml:lang="fr">Jordanie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Al Far, Rawhi" sort="Al Far, Rawhi" uniqKey="Al Far R" first="Rawhi" last="Al-Far">Rawhi Al-Far</name>
<affiliation wicri:level="1"><nlm:aff id="c">Faculty of Science and IT, Al-Balqa’a Applied University, Salt,<country>Jordan</country>
</nlm:aff>
<country xml:lang="fr">Jordanie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2012">2012</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en"><p>In the title salt, C<sub>6</sub>
H<sub>9</sub>
N<sub>2</sub>
<sup>+</sup>
·Br<sub>2</sub>
I<sup>−</sup>
, the cation is essentially planar (r.m.s. deviation = 0.0062 Å for the non-H atoms) while the anion is almost linear with a Br—I—Br angle of 177.67 (2)°. The crystal packing shows two anions and two cations connected <italic>via</italic>
 N—H⋯Br and (pyridine)N—H⋯Br hydrogen-bonding interactions, forming centrosymmetric tetramers with <italic>R<sub>4</sub>
<sup>4</sup>
</italic>
(16) ring motifs. Very weak offset aromatic π–π stacking interactions [centroid-centroid separation = 4.038 (4), slippage = 1.773 Å] also occur.</p>
</div>
</front>
<back><div1 type="bibliography"><listBibl><biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
</listBibl>
</div1>
</back>
</TEI>
<affiliations><list><country><li>Jordanie</li>
</country>
</list>
<tree><country name="Jordanie"><noRegion><name sortKey="Haddad, Salim F" sort="Haddad, Salim F" uniqKey="Haddad S" first="Salim F." last="Haddad">Salim F. Haddad</name>
</noRegion>
<name sortKey="Al Far, Rawhi" sort="Al Far, Rawhi" uniqKey="Al Far R" first="Rawhi" last="Al-Far">Rawhi Al-Far</name>
<name sortKey="Ali, Basem F" sort="Ali, Basem F" uniqKey="Ali B" first="Basem F." last="Ali">Basem F. Ali</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Sante/explor/MersV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 002290 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 002290 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Sante
   |area=    MersV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     PMC:3435817
   |texte=   2-Amino-5-methylpyridinium dibromoiodate
}}

Pour générer des pages wiki

HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i   -Sk "pubmed:22969663" \
       | HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd   \
       | NlmPubMed2Wicri -a MersV1

This area was generated with Dilib version V0.6.33.
Data generation: Mon Apr 20 23:26:43 2020. Site generation: Sat Mar 27 09:06:09 2021

Serveur d'exploration MERS

2-Amino-5-methylpyridinium dibromoiodate

2-Amino-5-methylpyridinium dibromoiodate

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

	Serveur d'exploration MERS
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration MERS

2-Amino-5-methyl­pyridinium dibromo­iodate

2-Amino-5-methyl­pyridinium dibromo­iodate

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

2-Amino-5-methylpyridinium dibromoiodate

2-Amino-5-methylpyridinium dibromoiodate